From the New York State Education Department. The University of the State of New York Regents High School Examination Physical Setting Chemistry January 2023. Internet. Available from https://www.nysedregents.org/Chemistry/123/chem12023-exam.pdf; accessed 3, May, 2023.
From the New York State Education Department. The University of the State of New York Regents High School Examination Physical Setting Chemistry January 2023. Internet. Available from https://www.nysedregents.org/Chemistry/123/chem12023-exam.pdf; accessed 3, May, 2023.
Scroll through the document embedded here to access the 2011 Edition Reference Tables for Physical Setting/Chemistry.
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Question 1
1.
Which conclusion was developed as a result of the gold foil experiment?
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Question 2
2.
Which two particles each have a mass approximately equal to one atomic mass unit?
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Question 3
3.
An excited potassium atom emits a specific amount of energy when one of its electrons moves from
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Question 4
4.
Which list of elements includes a metal, a metalloid, and a noble gas?
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Question 5
5.
Which element has the lowest density at 298 K and 101.3 kPa?
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Question 6
6.
Which phrase describes the crystal structure and properties of two different forms of solid carbon called diamond and graphite?
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Question 7
7.
Which element has chemical properties most similar to sodium?
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Question 8
8.
Which substance contains elements chemically combined in a fixed proportion?
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Question 9
9.
Which property can be used to differentiate between a 50.-gram sample of solid potassium nitrate at STP and a 50.-gram sample of solid silver chloride at STP?
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Question 10
10.
Which type of bond forms when electrons are equally shared between two atoms?
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Question 11
11.
Which statement describes the changes in bonding and energy that occur when a molecule of iodine, \mathrm{I_2}, forms two separate atoms of iodine?
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Question 12
12.
The degree of polarity in the bond between a hydrogen atom and an oxygen atom in a molecule of water can be assessed using the difference in
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Question 13
13.
Which substance can not be broken down by a chemical change?
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Question 14
14.
Which sample of matter is a mixture?
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Question 15
15.
Which term is used to express the concentration of an aqueous solution?
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Question 16
16.
The particles in which sample have the lowest average kinetic energy?
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Question 17
17.
Which process represents a chemical change?
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Question 18
18.
Which equation represents a physical equilibrium?
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Question 19
19.
Systems in nature tend to undergo changes toward
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Question 20
20.
Which formula represents a hydrocarbon?
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Question 21
21.
Which statement describes the bonding in an alkyne molecule?
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Question 22
22.
Which compound has a functional group that contains two oxygen atoms?
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Question 23
23.
Which term identifies a type of organic reaction?
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Question 24
24.
In an electrochemical cell, oxidation occurs at the
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Question 25
25.
Which energy conversion occurs in an operating electrolytic cell?
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Question 26
26.
One acid-base theory states that a base is an
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Question 27
27.
The acidity or alkalinity of a solution can be measured by its
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Question 28
28.
When the nucleus of an atom of neon-19 decays, which particle is emitted?
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Question 29
29.
Which nuclear emission has the greatest mass?
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Question 30
30.
Which statement describes the net change that occurs during nuclear fission?
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Question 31
31.
What is the net charge of a monatomic ion that has 15 protons, 16 neutrons, and 18 electrons?
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Question 32
32.
The table below shows the atomic masses and natural abundances of the two naturally occurring isotopes of rhenium.
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Question 33
33.
Which general trend is observed as the elements in Period 2 are considered from left to right?
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Question 34
34.
Which formula represents chromium(III) oxide?
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Question 35
35.
Given the balanced equation representing a reaction:
2KClO3 + energy \rightarrow 2KCl + 3O2
What is the mass of KCl produced when 24.51 grams of KClO3 reacts completely to produce 9.60 grams of O2?
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Question 36
36.
Which equation represents conservation of atoms?
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Question 37
37.
One mole of bromine gas, Br2, has a mass of
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Question 38
38.
Given the equation representing a reaction:
2NaCl \rightarrow 2Na + Cl2
Which type of reaction does this equation represent?
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Question 39
39.
Which statement describes the charge and the radius of the magnesium ion formed when a magnesium atom loses two electrons?
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Question 40
40.
An oxide ion, O2- has the same electron configuration as an atom of which noble gas?
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Question 41
41.
What is the vapor pressure of propanone at 45 degrees celsius?
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Question 42
42.
Based on Table G, what is the mass of \mathrm{KCl} that must be dissolved in 200. grams of H2O at 10.\degree\mathrm{C} to make a saturated solution?
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Question 43
43.
Based on Table I, which chemical equation represents a reaction with a heat of reaction that indicates a net release of energy?
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Question 44
44.
The greatest increase in entropy occurs when a 1.00-gram sample of water changes from
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Question 45
45.
Which particle diagram represents one substance, only?
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Question 46
46.
Based on Table J, atoms of which metal will lose electrons to \mathrm{Ca}^{2+} ions?
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Question 47
47.
Which aqueous solution is the best conductor of an electrical current?
Which formula represents an isomer of the compound?
Directions (51-65): Record your answers in the spaces provided. Some questions may require the use of the 2011 Edition Reference Tables for Physical Setting/Chemistry.
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Question 51
51.
Explain, in terms of neutrons and protons, why P-32 and P-31 are different isotopes of phosphorus.
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Question 52
52.
Determine the oxidation state of chromium in K2CrO4.
Base your answers to questions 53 and 54 on the information below and on your knowledge of chemistry.
The first four elements in Group 14 are carbon, silicon, germanium, and tin. These elements form compounds with chlorine that have similar formulas. Two examples of these formulas are silicon tetrachloride, SiCl4, and germanium tetrachloride, GeCl4.
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Question 53
53.
State the general trend in atomic radius as these four elements are considered in order of increasing atomic number.
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Question 54
54.
State, in terms of electron configuration, why silicon and germanium both form tetrachloride compounds.
Base your answers to questions 55 through 57 on the information below and on your knowledge of chemistry.
The equation to the left represents the reaction between ammonia and hydrogen chloride.
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Question 55
55.
Explain, in terms of distribution of charge, why a molecule of compound 1 is polar.
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Question 56
56.
Draw a Lewis electron-dot diagram for a molecule of compound 2.
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Question 57
57.
Identify the two types of chemical bonds in the product of this reaction.
Base your answers to questions 58 through 60 on the information below and on your knowledge of chemistry.
A sample of helium gas, \mathrm{He(g)}, is placed in a rigid cylinder sealed with a movable piston. The temperature of the helium is 25.0°C. The volume of the helium is 300. milliliters and the pressure is 0.500 atmosphere.
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Question 58
58.
State, in terms of the average distance between the helium atoms, why the density of the gas increases when the piston is pushed farther into the rigid cylinder.
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Question 59
59.
Determine the volume of the helium gas when the pressure is increased to 1.50 atm and the temperature remains at 25.0°C.
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Question 60
60.
Compare the number of helium atoms in the cylinder at a pressure of 0.500 atm to the number of helium atoms in the cylinder when the pressure is increased to 1.50 atm by pushing the piston in.
Base your answers to questions 61 and 62 on the information below and on your knowledge of chemistry.
During a laboratory activity, a student places 21.0 mL of hydrochloric acid solution, \mathrm{HCl(aq)}, of unknown concentration into a flask. The solution is titrated with 0.125 M \mathrm{NaOH(aq)} until the acid is exactly neutralized. The volume of \mathrm{NaOH(aq)} added is 18.5 milliliters. During this laboratory activity, appropriate safety equipment is used and safety procedures are followed.
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Question 61
61.
Explain, in terms of ions, why the hydrochloric acid solution can conduct an electric current.
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Question 62
62.
Determine the concentration of the \mathrm{HCl(aq)} solution, using the titration data.
Base your answers to questions 63 through 65 on the information below and on your knowledge of chemistry.
The table below lists the hydronium ion concentration and pH values of four different solutions and distilled water. The pH value is missing for sample 2.
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Question 63
63.
Determine the pH value of sample 2.
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Question 64
64.
Identify the ion released by the compound dissolved in sample 4 that allows the compound to be classified as an Arrhenius base.
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Question 65
65.
State how many times greater the hydronium ion concentration is in sample 4 than it is in sample 5.
Directions (66-85): Record your answers in the spaces provided. Some questions may require the use of the 2011 Edition Reference Tables for Physical Setting/Chemistry.
Base your answers to questions 66 through 68 on the information below and on your knowledge of chemistry.
Boric acid, H3BO3, is heated to produce tetraboric acid, H2B4O7, and water. The equation below represents the reaction to form tetraboric acid.
The tetraboric acid is then used to make borax, which is used as a cleaning agent. Borax, Na2B4O7.
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Question 66
66.
Explain why the formula for tetraboric acid is an empirical formula.
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Question 67
67.
Determine the number of moles of boric acid that react in the equation to produce 10 moles of water.
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Question 68
68.
Show a numerical setup for calculating the mass, in grams, of a 0.200-mole sample of borax.
Base your answers to questions 69 through 71 on the information below and on your knowledge of chemistry.
During a laboratory activity, appropriate safety equipment is used and safety procedures are followed. A student uses the lab equipment shown in the diagram below to determine the heat of combustion of candle wax.
Heat of combustion is defined as the amount of heat released when a known mass of a substance is burned and can be measured in joules per gram. At the start of the activity, the mass of the candle and the mass of the water are measured. The starting temperature of the water is 5.0°C, and the air temperature in the room is 22.0°C. The candle is lit, and the water is stirred with a stirring rod. Several minutes later, the candle is extinguished, and the student measures the temperature of the water in the can. When the candle is cool, the student measures the final mass of the candle. Lab activity results are shown in the table below.
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Question 69
69.
State the number of significant figures used to express the value for the mass of the water in the can.
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Question 70
70.
State the direction of the heat flow between the air and the water in the can before the candle is lit.
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Question 71
71.
Determine the amount of heat absorbed by the water.
Base your answers to questions 72 through 76 on the information below and on your knowledge of chemistry.
A process was developed in 1912 to produce ammonia gas from atmospheric nitrogen gas and hydrogen gas. Iron can be used as a catalyst. The equation representing this system at equilibrium is shown below.
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Question 72
72.
State evidence from the equation that the forward reaction is exothermic.
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Question 73
73.
Compare the rate of the forward reaction to the rate of the reverse reaction at equilibrium.
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Question 74
74.
On the labeled axes in the Show Your Work space, draw a potential energy diagram for the forward reaction represented in this equation.
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Question 75
75.
State, in terms of moles of gases, why the equilibrium shifts to the right due to an increase in pressure on the system at constant temperature.
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Question 76
76.
State what happens to the rate of forward reaction when the iron is added to this system.
Base your answers to questions 77 through 79 on the information below and on your knowledge of chemistry.
Before the year 1828, it was thought that organic compounds were produced only by living organisms and that inorganic compounds were made from nonliving substances. Urea is an organic compound. In 1828, a chemist heated ammonium cyanate and produced urea, which is very soluble in water. The equation below represents this reaction.
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Question 77
77.
Identify the element present in urea that is present in all organic compounds.
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Question 78
78.
Compare the formula mass of the two compounds in the equation.
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Question 79
79.
State, in terms of molecular polarity, why urea is very soluble in water.
Base your answers to questions 80 and 81 on the information below and on your knowledge of chemistry.
When a voltmeter is connected in the circuit of a voltaic cell, an electrical measurement called voltage can be read on the meter. The voltage of the cell is affected if the concentration of the solute in the half-cells is changed. The diagram, the ionic equation, and the graph below represent a copper-zinc cell. When the switch is closed, electricity flows through the circuit as the cell operates at constant temperature.
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Question 80
80.
Based on the graph, determine the voltage of the cell if the Cu(NO3)2(aq) concentration is 1.5M.
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Question 81
81.
Write a balanced half-reaction equation for the oxidation of zinc that occurs in this operating cell.
Base your answers to questions 82 through 85 on the information below and on your knowledge of chemistry.
Synthetic radioisotopes may be made by bombarding other nuclides with neutrons. The equations below represent a sequence of reactions converting stable iron–58 to cobalt–60, which is used in medical treatments.
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Question 82
82.
State the neutron to proton ratio for an atom of the ^{58}\mathrm{Fe} in equation 1.
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Question 83
83.
State, in terms of elements, why equation 2 represents a transmutation reaction.
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Question 84
84.
Identify the particle represented by X in equation 3.
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Question 85
85.
Determine the fraction of an original sample of Co-60 that remains unchanged after 15.813 years.